* If it is from the early 1980s, she could very well be Star Stowe.
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* If it is from 2001, otherwise, she is probably just another Kiss groupie.
Gene Simmons and Paul Stanley have had hundreds of girls. Maybe thousands during their careers. They were known as hard drinkers and hard womanizers.
This below is from Gene Simmons' wikipedia entry:
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If this is during the early 1980s -- then this definitely is a few years before he met Shannon Tweed --
Playboy's Playmate of the Year for 1982. They've been in a relationship since 1983. Gene has been pretty much on the up and up with her. Very faithful.
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In Summary:
1. So if this is during the early 1980s then this is Star Stowe.
2. If just like the OP says, it's from 2001 during the release of their box set, then I'd tend to think she is just a groupie.