In my mind its a close tie between mgs and mgs3
i think mgs3 gave Hideo the graphics ability to make a real dynamic game, plus it had Harry Gregson Williams scoring it.
Either way, both groundbreaking.
No one beats Codi Milo in my mind
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CODI MILO (the one girl who has stayed my favorite the longest)
http://galleries.danni.com/100190/photos/cody_milo/
http://galleries.suze.net/100190/models/codimilo/index.html
http://fhg.digitaldreamgirls.com/gals/cody_milo/100190
she also does my fav gg gallery...